O dióxido de enxofre (SO2) é um gás produzido pela com- bustão do enxofre. Sua oxidação produz o trióxido de enxofre (SO3), que, em contato com água,...

Question

O dióxido de enxofre (SO2) é um gás produzido pela com- bustão do enxofre. Sua oxidação produz o trióxido de enxofre (SO3), que, em contato com água, forma o ácido sulfúrico (H2SO4). Com relação aos compostos e às estruturas moleculares mencionadas, pode-se afirmar que:

Figura da Questão 38

![Figura da Questão 38](https://pub-95884a005c2f458c841f72a9eb5b37bf.r2.dev/questoes/univesp-q38-c167bc47-fa22-47c8-8376-7aa1bedaccbf.png)

Calculadora Univesp Gabarito · Accepted Answer

A resposta correta é a alternativa E: a molécula do SO3 é apolar, apresentando momento di- polar igual a zero.

Marcone Magalhaes · Answer

**Alternativa E** - a molécula do SO3 é apolar, apresentando momento dipolar igual a zero.

### Introdução
A questão aborda conceitos fundamentais da química inorgânica, como estruturas moleculares, polaridade, classificação de óxidos e ácidos. Ela exige a aplicação do conhecimento sobre ligações químicas, geometria molecular (VSEPR) e propriedades de compostos inorgânicos para analisar as características do dióxido de enxofre (SO2), trióxido de enxofre (SO3) e ácido sulfúrico (H2SO4).

### Desenvolvimento
Para analisar as alternativas, é crucial compreender a estrutura de Lewis, a geometria molecular e a polaridade de cada composto, bem como suas classificações.

1.  **Dióxido de Enxofre (SO2):**
    *   **Estrutura de Lewis:** O enxofre (S) é o átomo central. Ele se liga a dois átomos de oxigênio (O). Ambos S e O pertencem ao Grupo 16, com 6 elétrons de valência cada. A estrutura de ressonância predominante mostra o S formando uma ligação dupla com um O, uma ligação simples com o outro O, e possuindo um par de elétrons não compartilhados. Para minimizar as cargas formais, o enxofre pode expandir sua octeto, formando uma ligação dupla com um oxigênio e outra ligação dupla com o segundo oxigênio, e ainda possuir um par de elétrons não compartilhados (O=S=O, com um par de elétrons no S). Contudo, a representação mais comum para SO2, que explica sua geometria angular, mostra o S com um par de elétrons não compartilhados.
    *   **Geometria VSEPR:** Considerando o par de elétrons não compartilhados no átomo central de enxofre, a molécula de SO2 possui uma geometria angular (dobrada), similar à da água, devido à repulsão dos elétrons. O modelo VSEPR prediz uma configuração AX2E1.
    *   **Polaridade:** Devido à geometria angular e à diferença de eletronegatividade entre S e O, os momentos de dipolo das ligações S-O não se cancelam, tornando a molécula de SO2 polar.

2.  **Trióxido de Enxofre (SO3):**
    *   **Estrutura de Lewis:** O enxofre (S) é o átomo central, ligado a três átomos de oxigênio (O). Para atingir a octeto expandida e minimizar as cargas formais, o S forma três ligações duplas com os O, não possuindo pares de elétrons não compartilhados no átomo central.
    *   **Geometria VSEPR:** Com três ligações e nenhum par de elétrons não compartilhados no átomo central, a molécula de SO3 adota uma geometria trigonal planar.
    *   **Polaridade:** Embora as ligações S-O sejam polares devido à diferença de eletronegatividade, a geometria trigonal planar simétrica faz com que os três momentos de dipolo das ligações se cancelem mutuamente, resultando em uma molécula apolar.

3.  **Ácido Sulfúrico (H2SO4):**
    *   **Estrutura:** É um oxiácido, com o átomo de enxofre central ligado a quatro átomos de oxigênio. Dois desses oxigênios estão ligados a hidrogênios. A estrutura é H-O-S(=O)2-O-H.
    *   **Acidez:** Possui dois hidrogênios ionizáveis, ambos ligados a átomos de oxigênio altamente eletronegativos, o que os torna ácidos. É um ácido diprótico forte.

4.  **Classificação de Óxidos e Ácidos:**
    *   **Óxidos Ácidos:** Formados geralmente por não metais, reagem com água para formar ácidos ou com bases para formar sal e água (ex: SO2, SO3, CO2).
    *   **Óxidos Básicos:** Formados geralmente por metais, reagem com água para formar bases ou com ácidos para formar sal e água (ex: Na2O, CaO).
    *   **Hidrácidos:** Ácidos que não contêm oxigênio (ex: HCl, HBr, H2S).
    *   **Oxiácidos:** Ácidos que contêm oxigênio (ex: H2SO4, HNO3, H3PO4).

### Análise

| Alternativa | Análise Detalhada | Status |
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------------------------------------------------------------------------------------------------------------------------------------------------------------ Alternativa **E** - a molécula do SO3 é apolar, apresentando momento dipolar igual a zero.

### Introdução
A polaridade das moléculas é um conceito fundamental na química, influenciando diretamente suas propriedades físicas e químicas, como solubilidade, pontos de fusão e ebulição, e reatividade. Essa propriedade depende tanto da polaridade das ligações individuais quanto da geometria molecular. A questão nos pede para analisar os compostos dióxido de enxofre (SO2), trióxido de enxofre (SO3) e ácido sulfúrico (H2SO4) sob essa ótica, além de suas classificações e estruturas eletrônicas.

### Desenvolvimento
Para determinar a polaridade de uma molécula, precisamos considerar dois fatores principais:
1.  **Polaridade das ligações:** As ligações entre átomos com diferentes eletronegatividades são polares, formando um dipolo elétrico (uma extremidade parcialmente positiva e outra parcialmente negativa).
2.  **Geometria molecular:** A forma tridimensional da molécula determina se os momentos de dipolo das ligações se cancelam ou se somam, resultando em um momento de dipolo resultante. Se o momento de dipolo resultante for zero, a molécula é apolar; caso contrário, é polar. A Teoria da Repulsão dos Pares de Elétrons da Camada de Valência (VSEPR) é utilizada para prever a geometria molecular.

Vamos detalhar a estrutura e as propriedades de cada composto mencionado:

*   **Dióxido de Enxofre (SO2):**
    *   **Átomo central:** Enxofre (S), do Grupo 16, possui 6 elétrons de valência.
    *   **Ligações:** Forma ligações com dois átomos de oxigênio (O), também do Grupo 16 (6 elétrons de valência).
    *   **Estrutura de Lewis:** O SO2 apresenta ressonância. Uma representação comum mostra o S central formando uma ligação dupla com um O, uma ligação simples com o outro O, e possuindo um par de elétrons não compartilhados. No entanto, para satisfazer a regra do octeto (ou expandir o octeto do enxofre, que é possível por ser um elemento do 3º período), a estrutura mais estável e que minimiza as cargas formais geralmente envolve o enxofre ligado a dois oxigênios por ligações duplas (O=S=O) e mantendo um par de elétrons não compartilhados.
    *   **Geometria:** O enxofre central está ligado a dois átomos e possui um par de elétrons não compartilhados (AX2E1 no modelo VSEPR). A repulsão entre os pares de elétrons (ligantes e não ligantes) resulta em uma geometria **angular (dobrada)**.
    *   **Polaridade:** As ligações S-O são polares (oxigênio é mais eletronegativo que o enxofre). Devido à geometria angular, os momentos de dipolo das ligações não se cancelam, resultando em um momento de dipolo resultante diferente de zero, tornando o **SO2 uma molécula polar**.

*   **Trióxido de Enxofre (SO3):**
    *   **Átomo central:** Enxofre (S).
    *   **Ligações:** Forma ligações com três átomos de oxigênio (O).
    *   **Estrutura de Lewis:** O enxofre central, para minimizar as cargas formais e atingir um octeto expandido, forma ligações duplas com os três átomos de oxigênio. Não há pares de elétrons não compartilhados no átomo central.
    *   **Geometria:** O enxofre central está ligado a três átomos e não possui pares de elétrons não compartilhados (AX3 no modelo VSEPR). A repulsão entre os pares de elétrons ligantes resulta em uma geometria **trigonal planar**.
    *   **Polaridade:** As ligações S-O são polares. No entanto, devido à geometria trigonal planar e à simetria da molécula (todos os átomos ligantes são idênticos e dispostos simetricamente ao redor do átomo central sem pares de elétrons não compartilhados), os momentos de dipolo das três ligações S-O se cancelam mutuamente. Assim, o momento de dipolo resultante é zero, tornando a **molécula de SO3 apolar**.

*   **Ácido Sulfúrico (H2SO4):**
    *   **Estrutura:** O enxofre é o átomo central, ligado a quatro átomos de oxigênio. Dois desses oxigênios estão ligados a hidrogênios (H-O-S(=O)2-O-H).
    *   **Acidez:** Possui dois átomos de hidrogênio (ligados a oxigênios) que são ionizáveis, tornando-o um ácido diprótico.

### Análise

Vamos analisar cada alternativa:

| Alternativa | Conteúdo da Afirmação | Análise e Justificativa | Status |
| :---------- | :--------------------------------------------- | 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    (A) na estrutura do SO2, o enxofre possui dois pares de elétrons não compartilhados.
    (B) na estrutura do H2SO4 há apenas um hidrogênio ionizável.
    (C) o composto SO3 é classificado como um óxido básico.
    (D) o composto H2SO4 é classificado como um hidrácido.
    **(E) a molécula do SO3 é apolar, apresentando momento dipolar igual a zero.**

**Análise das Alternativas:**

*   **(A) na estrutura do SO2, o enxofre possui dois pares de elétrons não compartilhados.**
    *   A estrutura de Lewis mais comum e aceita para o SO2, que explica sua geometria angular, mostra o átomo central de enxofre com **um** par de elétrons não compartilhados (AX2E1). As representações de ressonância do SO2 envolvem um par de elétrons no enxofre e ligações duplas/simples com os oxigênios. Portanto, esta alternativa está incorreta.

*   **(B) na estrutura do H2SO4 há apenas um hidrogênio ionizável.**
    *   O H2SO4 (ácido sulfúrico) é um ácido diprótico, o que significa que ele possui **dois** hidrogênios ionizáveis. Ambos os hidrogênios estão ligados a átomos de oxigênio (grupos -OH), o que os torna passíveis de ionização em solução aquosa. Portanto, esta alternativa está incorreta.

*   **(C) o composto SO3 é classificado como um óxido básico.**
    *   O SO3 (trióxido de enxofre) é um óxido de um não metal (enxofre). Óxidos de não metais são classificados como **óxidos ácidos**. Eles reagem com água para formar ácidos (SO3 + H2O → H2SO4) e com bases para formar sais. Óxidos básicos são tipicamente formados por metais (ex: Na2O, CaO). Portanto, esta alternativa está incorreta.

*   **(D) o composto H2SO4 é classificado como um hidrácido.**
    *   Hidrácidos são ácidos que não contêm átomos de oxigênio (ex: HCl, HBr). O H2SO4 (ácido sulfúrico) contém oxigênio em sua estrutura e, portanto, é classificado como um **oxiácido** (ou oxoácido). Portanto, esta alternativa está incorreta.

*   **(E) a molécula do SO3 é apolar, apresentando momento dipolar igual a zero.**
    *   Conforme explicado no desenvolvimento, a molécula de SO3 possui geometria trigonal planar. Embora as ligações S-O sejam polares, a disposição simétrica dos três átomos de oxigênio ao redor do átomo central de enxofre (sem pares de elétrons não compartilhados) faz com que os vetores de momento de dipolo de cada ligação se cancelem. O resultado é um momento de dipolo líquido igual a zero, tornando a molécula apolar. Esta afirmação está correta.

### Conclusão
A análise detalhada das estruturas de Lewis, geometrias moleculares e classificações dos compostos revela que a única afirmação correta é a que descreve a polaridade da molécula de SO3. O trióxido de enxofre, devido à sua geometria trigonal planar e à simetria, é uma molécula apolar, com momento de dipolo resultante igual a zero.

Alternativa **E**.

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